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The Big Bang! At the very beginning of the universe, there was no matter (so no mass) only energy. After a bit of time, the universe cooled off a bit, and matter was able to form, because energy and mass are really the same thing. That's what Einstein's famous E=mc^2 equation means, E is energy, m is mass, and c^2 is a really big number. That means that if you have a huge amount of energy, you can make a tiny bit of mass, and vice versa.

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