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The answer is (ii) Nitrogen dioxide. Nitrogen is available in air in bonded form N2. Lightning energy helps break this N2 bond and produces nitrogen ions. These ions combine with Oxygen to produce Nitrogen monoxide in the first step and then nitrogen dioxide.

If there happens to be rain at the time of lightning, this NO2 dissolves in water to form nitric or nitrous acids and falls to earth. These acids are in usable form for many plants. This process is one of the ways for nitrogen fixation in the environment. Kalra

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