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Electrons are negatively charged, and so are some ions. It depends what ion you are talking about. All atoms start off neutral, because they have the same number of protons and electrons. When they become ions, they gain charge. For instance, a sodium chloride ion (NaCl) the metal ion, sodium, becomes positively charged because it loses one negatively charged particle (an electron). Chlorine then becomes negative, because it has gained a negatively charged electron.

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