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Gases are airbourne, whereas liquids are typically limited in how they travel by the path available and gravity. It's much easier to disperse a gas than a liquid, plus gases tend to be much less obvious - carbon monoxide, for instance, is a lethal gas which is both odourless and colourless.

It depends what you mean by 'affected', drinking or injecting a toxic liquid might be far worse than breathing in a similar toxic gas. As mentioned above gases are airborne and are harder to contain.

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Which areas on earth would people most likely be affected by an ozone hole?

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