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Most volcanoes form at either convergent or divergent plate boundaries. Volcanoes at convergent plate boundaries form when one plate slides under another, taking seawater with it. This causes the rock in the mantle to melt as the melting point drops. This new magma can rise to form volcanoes.
At divergent plate boundaries the crust is thing, which lowers pressure on the mantle, causing some material to melt.

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