Why can't polymers be analysed by gas chromatography?

Answer 1

polymers are not volatile.. therefore, can't be separated by Gas Chromatography

Answer 2

Polymers are too large and complex to be vaporized and separated by gas chromatography. Gas chromatography is typically used for analyzing small molecules with low molecular weight, as they can be vaporized and pass through the column more easily for separation. Polymers, being much larger, tend to degrade or decompose when subjected to the high temperatures of the gas chromatography column.