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It is to do with the surface tension (ST). Mercury has very big ST. Water will form droplets too but on the oily surface. This is because water molecules form hydrogen bonds and the oily (organic) matter cannot form them. Thus, thermodynamically it is more favourable for water to have as little interactions with the organic surface as possible. This is achieved by reducing the surface area in forming a droplet.

In a liquid a sort of internal pressure is created because the molecules that are inside (in the bulk) are pulled into all the possible directions, owever the molecules on the surface lack some of the pull. Therefore, they have higher energy and are pulled more inwards than outward. If you imagine all the molecules at the surface (when we imagine the hypothetical liquid being spread a lot) to be pulled in, the matter will 'pack' itself into the lower energy shape with reduced surface area - droplet.

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