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it actually does not. intersystem crossing is what creates the triple state not what reduces it to its ground state. it happens in a series of steps... first you have the excited singlet state created by photon absorption which would generally immediately emit flouresence to return to the ground state. however, if it does not emit flouresence than it becomes subject to intersystem crossing (ISC). ISC can cause an electron to invert its rotation and begin the same orbital rotation path of another electron, therefore creating the triplet state (two electrons having same directional orbit). the triplet state then undergoes internal conversion, again altering those two electrons in question. Now, when the triplet is reduced to the ground state it emits phosphorescence instead of flourescence.

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