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Iron-59 has 33 neutrons because its atomic number is 26, which means it has 26 protons. The mass number of iron-59 is 59, which is the sum of protons and neutrons in the nucleus. To find the number of neutrons, you subtract the number of protons from the mass number: 59 (mass number) - 26 (protons) = 33 neutrons.

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