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I think it is the ortho position that has a smaller band and this is due to van der waals interactions

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15y ago

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What information can be obtained from a broad peak in an IR spectrum?

A broad peak in an infrared (IR) spectrum can provide information about the presence of functional groups with hydrogen bonding or multiple types of bonds. It can indicate the presence of molecules such as alcohols, carboxylic acids, or amines.


Why could the IR spectrum of a sample which is contaminated with water lead to an erroneous conclusion that the compound is an alcohol or a phenol?

Water can give a broad peak in the IR spectrum in the same region as the hydroxyl (OH) stretch of alcohols and phenols, leading to confusion. This overlap can result in misinterpretation of the peak as being due to the presence of an alcohol or phenol group when it is actually from water contamination. It is important to ensure the sample is properly dried before analyzing it to avoid this issue.


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