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As the comet approaches the sun, it gets heated up, and its surface begins to turn into a gas (sublimates). The gas then escapes from the comet, and with enough force to blow away some dust and small rocks from the comet. This dust and gas is what makes the tail and also why the tail always points away from the sun (even when the comet is running from the sun, so the tail is in frount of the comet).

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