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Ionic azides are more stable than covalent azides primarily due to the strong electrostatic interactions between the positively charged cation and the negatively charged azide ion (N₃⁻). This ionic bonding provides a more stable lattice structure, while covalent azides rely on weaker covalent bonds that can be more susceptible to decomposition. Additionally, the azide ion has a resonance stabilization that can further enhance the stability of ionic azides compared to their covalent counterparts.

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1d ago

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