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CrO₄²⁻ (chromate ion) is a strong oxidizing agent because it can readily accept electrons due to its high oxidation state of chromium, allowing it to facilitate oxidation reactions. In contrast, MnO₄⁻ (permanganate ion) is a strong oxidizing agent, but MnO₄²⁻ (manganate ion) is less effective because manganese in the +6 oxidation state (in MnO₄²⁻) is less willing to accept electrons compared to chromium in CrO₄²⁻. The effective oxidation states and the stability of the resulting products after reduction contribute to the differences in their oxidizing strengths.

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Why Cro42- is a strong oxidising agent but MnO42- not?

Cro42- (chromate ion) is a strong oxidizing agent because it can readily accept electrons, undergoing reduction to Cr3+ in acidic conditions. Its high oxidation state and the stability of the resulting lower oxidation state make it effective in oxidizing other substances. In contrast, MnO42- (manganate ion) is a weaker oxidizing agent because, while it can also accept electrons, its reduction to Mn2+ is less favorable compared to the reduction of chromate. Additionally, the presence of additional oxidation states for manganese allows for more stable intermediates, diminishing its overall oxidizing strength.


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