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Metals are usually good conductors of heat and non-metals are poor conductors. This is put down to metals having many free electrons which move easily and transfer heat from one part of the metal sample to another, whereas non-metals do not have free electrons and can only conduct heat from atom to atom.

Thus silver and copper are good thermal conductors whilst air and cork and wood are poor ones. Silver and copper are also good electrical conductors and the others mentioned poor electrical conductors, and there is some correlation here between the two types of conduction.

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