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Drawing the solvent front immediately after removing the plate from the developing chamber is crucial for accurate measurement and reproducibility in chromatography. This line indicates the maximum extent to which the solvent has traveled, allowing for the calculation of retention factors (Rf values) for the separated compounds. If the solvent front is not marked promptly, it may continue to spread or evaporate, leading to inaccurate results and difficulties in comparing experiments. Timely documentation ensures consistency and reliability in analytical processes.

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