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It's precisely because it's so eager to get to the diatomic triple-bonded state. N2 is an incredibly stable molecule. There are few organisms capable of ripping it apart and fixing it into a biological useful state; most importantly, bacteria that live on certain plants' roots. This is why nitrogen is so important in fertilizer.

Anyway, when you convert an unstable nitrogen compound (at a reasonably high energy state) into that incredibly stable N2 (at a very low energy state), the huge difference in energy is released. If the difference is big enough, it's released as a big boom.

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