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A monatomic gas has no contribution from vibration to its specific heat. A diatomic gas has both vibration of the two atoms as the stretch and compress the bond between them and can rotate faster or slower. With more ways to store energy than just translational energy, diatomic gases tend to have higher heat capacities.

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Why is the molar specific heat of a diatomic gas usually larger than that of monoatomic gas?

Diatomic gases have more degrees of freedom. They are also larger in size and mass. specific heat is proportional to the number of degrees of freedom; monatomic gases can only move linearly and have 3 degrees of freedom, molecules can also rotate and vibrate, so have more degrees of freedom.


Why is the molar specific heat of diatomic gas larger than that of a monoatomic gas?

Diatomic gases have more degrees of freedom. They are also larger in size and mass. specific heat is proportional to the number of degrees of freedom; monatomic gases can only move linearly and have 3 degrees of freedom, molecules can also rotate and vibrate, so have more degrees of freedom.


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