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The presumption 'salts are neutral' is, generally speaking, not true.

Only salts from

  • anions conjugated with strong acids (like Cl- and NO3-)

    and

  • cations from earth alkali and alkali metal ions (mono- and di-valent positives)
are neutral.

Acetates, sulfides, carbonates are weakly basic salts (pH>9.5) because they can 'absorb' some H+ from water, thus leaving a small excess OH- ions to raise pH above neutral.

On the otherhand (trivalent) Al-nitrate and Fe(III)-chloride aare weakly acid (pH<4.5) because they 'absorb' some OH- from water, thus leaving a small excess H+ ions to lower pH beyond neutral value 7.

Last but not least: ammonium (NH4+)-salts are acidic because it is directly conjugated to the basic NH3:

NH4+ <--> NH3 + H+

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11y ago

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