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The basic principle of both theories is same that is distribution of electrons but mot is superior to vbt. The reason is that vbt could not explain paramagnetic character of oxygen while the mot has sucessfully explain the paramagnetic character of oxygen.

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Why mot is superior to vbt?

MOT (Molecular Orbital Theory) is often considered superior to VBT (Valence Bond Theory) because it provides a more comprehensive explanation of molecular bonding and properties. While VBT focuses on localized electron pairs between atoms, MOT accounts for the delocalization of electrons across the entire molecule, thus better explaining phenomena like resonance and magnetic properties. Additionally, MOT can accurately describe the behavior of molecules that do not conform to simple bond formations, such as those with multiple bonding or unusual geometries. This broader applicability makes MOT a more powerful tool in understanding complex molecular systems.


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