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The four laws of thermodynamics are:

  • Zeroth law of thermodynamics: If two systems are in thermal equilibrium with a third system, they must be in thermal equilibrium with each other. This law helps define the notion of temperature.
  • First law of thermodynamics: Heat is a form of energy.Because energy is conserved, the internal energy of a system changes as heat flows in or out of it. Equivalently, perpetual motion machines of the first kind are impossible.
  • Second law of thermodynamics: The entropy of any closed system not in thermal equilibrium almost always increases.Closed systems spontaneously evolve towards thermal equilibrium -- the state of maximum entropy of the system. Equivalently, perpetual motion machines of the second kind are impossible.
  • Third law of thermodynamics: The entropy of a system approaches a constant value as the temperature approaches zero.The entropy of a system at absolute zero is typically zero, and in all cases is determined only by the number of different ground states it has.
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