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Well, if you look at it in a purely elemental capacity we see trends that with an increase in electron shielding, we get a decrease in melting point.

This is said to be because with larger electron shielding we have a lower Z(eff) (effective nuclear charge) between atoms meaning weaker forces keeping them together and thus a lower melting point.

I think this is an important logical procedure when understanding why things melt and what things like Z(eff) really mean in terms of an atom's behaviour. It's a good learning tool but, outside of periodicity, I would never feel comfortable attributing a melting point to electron shielding. Good idea for elements, terrible idea for molecules.

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Q: What does electron shielding have to do with melting points?
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Why is electron shielding not a factor when you examine a trend across a period?

Electron shielding is not a factor across a period because they all have the same number of electron shells! No further (extra) shells means that they are all affected by electron shielding equally.


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