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n is the principal quantum number and represents the energy level or electron shell in which an electron resides.

For example - Say you have an Oxygen atom, which has 8 electrons. It's electron configuration is 1s2 2s2 2p4. The 2 in 2p4 is the principle quantum number, n. The s is another term dealing with angular momentum and the 4 is the number of electrons.

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