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The currently accepted model of the Big Bang predicts that the early universe was composed of a quark-gluon plasma. After it cooled, baryons could form (baryons are particles like protons and neutrons which are made of quarks), and some time after that atoms could form.

If you mean which was DISCOVERED first, atoms, by at least a couple of centuries.

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10y ago
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14y ago

atoms i think. the first atomic theories were around the 1930's and quarks were proposed in the 1960's

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Q: Which came into existence first atoms or quarks?
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