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The Third Law of Motion, which states that for a given force, there is an equal reaction force. Burned fuel exits a rocket's backside, and the rocket moves forward.

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The third law applies here. For every action there is an equal and opposite reaction. When the rocket fuel is ignited it exerts enormous thrust directed downwards. If the rocket is not constrained to the launching pad (with very very heavy restraints) it sees no other way to nullify the enormous thrust but to set itself in motion. Soon as more fuel burns, the rocket accelerates. As a side, if the rocket was restrained with very heavy agents, these agents (in the form of nuts and bolts or whatever) will have to bear the thrust of the rocket engine.