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Because heat is a measure of motion and energy of the atoms in a given substance. The more that atoms are moving around the greater the temperature. On the same note, the more motion between atoms the more spaced out and less organized they become. therefore with the exception of water the best way to condense a material (liquid or otherwise) is to cool it. search your science textbooks for "Laws of Thermodynamics". This is the best I can do from memory

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