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Because they absorb them better. If a surface were to absorb a certain radiation very well and not radiate it well, an apparatus could be made that violates the Second Law of Thermodynamics (creating a temperature difference where none existed previously). Therefore, it is not possible.

You might also say that the dark surface is "transparent in both directions" (in and out). This is for a specific radiation; on the other hand, it is possible to have surfaces that radiate and absorb electromagnetic waves of one frequency well, and not so well at other frequencies.

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Q: Why do dark surface3s radiate heat better?
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