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When we pass electricity through a gas , the gas molecules get excited and give out electrons and the gas molecules become positively charge (form ions).

As the ions are positively charged and the electrons are negatively charged they have a tendency to recombine and for a neutral gas molecule again.

(Note- High pressure=molecules are more close [more crowding]

Low Pressure=molecules are not so close[less crowding] )

At atmospheric pressure the gas molecules are more closer to each other that's why they recombine easily avoiding the electrons to flow.

At low pressure the gas molecules are not so close and hence it is difficult for the ion and the electron to recombine and form a neutral molecule.

This results into flow of electrons and hence the gas starts to act as an conductor.

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