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It is a mortal sin because it is against the Natural Law and against God's plan for marriage. This is a huge topic, but the basics are that the only natural right that a husband and wife have, from God, is the right to each other's bodies. They do not have a "right" to a child. Children are a gift from God - in every circumstance, and when we abrogate to ourselves a right which we do not have, and play God in this manner, we are perverting the natural order and committing sin. All other rights are the rights of a child, not the parents, and the child has a natural right to be born in ordinary circumstances, the effects of this sin are visited upon the child conceived in this way. Science is just now telling us of all the problems that children who were conceived in this way have as they grow up. For a doctor answering this question, please see the link below to a brief clip on Catholic Answers.

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