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Nicotine

It depends how you define "drug". Nicotine is not an illegal drug, like cocaine. Nicotine is claimed to be addictive, but so are alcohol and junk food. Nicotine patches, etc, may be bought in pharmacies, like pain-killers. A drug may be prescribed by a doctor to treat a medical condition and the pharmaceutical industry is trialling nicotine-based drugs to treat pain and treat a whole range of conditions from Tourettes to Parkinsons.

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