There are two different versions to how Achilles mother (Thetis) made him invulnerable.
The first is that she dipped Achilles into the river Styx and held him by his heel thus making all but his heel invulnerable which was eventually his downfall.
The second was that Thetis covered him in ambrosia and was burning away his mortality the house fire, Peleus discovering the plan snatched Achilles away before Thetis could finish his heel.
I hope this helps and if you want to read about it yourself.
http://en.wikipedia.org/wiki/Achilles%27_heel
This gives you the basic idea of these two versions.
Paris who was Hectors brother shot him with an arrow in the ankle heel part. When Achilles was a baby his mom dipped him in a magical river that made the Gods look after him. When she dipped baby Achilles in the water he was held by his heel there fore that was his weak spot so when Paris hit him it made him die.
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She dipped him in the river styx.
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it's a really facinating history. Achillies was born and his mom dipped him into the river styx and he became unvunereble except for one of his heels at which his mom was holding him for. so a war came and Achilles attacke the enemy's govenor there were more wars then in the France War someone shot Achilles by the ankle and he died thus his ankle is worshipped.
Achilles was dipped into river Styx by the heel when he was a baby and in ancient Greek legends the river would make you invincible but you had to have a weak spot so achilles heel was his weak spot. So the term Achilles heel is used it means your weak spot.
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