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If you include the European portion of Russia, the second largest country in Europe is France, by area. If you only include parts in Europe however, then Ukraine is second by area. By population, the second largest country would be Germany (83,000,000) second to Russia (140,000,000 total; 110,000,000 in Europe)

If you do not include European Russia, then Ukraine is second (France would be first including integral parts not located in Europe). If only parts in Europe are included, then France is second by area. By population, the second largest country would be France (65,000,000 total; 63,000,000 in Europe) second to Germany (83,000,000)

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