Unless it's a privately-minted bullion piece it would be either a standard Peace dollar dated 1921 to 1935, or a .999 fine Walking Liberty "dollar" dated 1986 or later. It can't be both.
If it's a genuine Peace dollar it's .900 fine, not .999; its value depends on its date and mint mark but will be at least $14 for the silver it contains. If it's a .999 bullion piece its value will be a bit more than the current spot price of silver as given in your newspaper or at a site such as kitco.com.
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1896S .999 fine gold
Oh, dude, a 1999 silver dollar with Lady Liberty painted on it is worth about the same as a regular 1999 silver dollar. The paint doesn't really add any extra value, unless maybe it was painted by Lady Liberty herself, but I highly doubt that. So, like, you're looking at around $20-30 depending on the condition and market demand.
it depends weather this coin is a dollar, half dollar, quarter, nickel, half dime, or dime. they made draped bust types for all of these denominations. together with varying mint marks, dates, and grades, the amount could be virtually anything. send more specific information. also, they are not .999 silver, they are varying .8924, and .900 silver
The Chief 1899 $5 dollar silver certificate is paper money.
Several different copies have been made, so this is impossible to answer without more detail. Some are struck in .999 fine silver, some in coin silver(.90 fine) and some in base metals. Some are very close in design to the original and some are only similar. They seem to cost $25-50 from the manufacturer and sell on eBay for $3-$20.