For general circulation, 1964.
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1964 was the last year US quarters were made of Silver.
1964 was the last year the US produced silver quarters for circulation.
All quarters dated 1964 and before are silver, all quarters released for general circulation dated 1965-present are not silver. The US mint has released quarters struck in 40% silver for collectors during the US Bicentennial and 90% silver proof sets for collectors in 1992-present.
1964 was the last year for 90% silver quarters made for everyday use, all quarters from 1965 to the present are copper-nickel.
The last year for silver quarters was 1964.