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i am a Pokemon master and i say yes you can You can catch pikachu by going to the Safari Zone in Ruby and then go into the grass in the safari zone and you will find a pikachu edventually.

First you need a Acro Bike from the Mauville bike shop. Then you need a Pokemon that know's sweet scent (Tropius). Then you go to the Safari Zone and use the Acro Bike to go on the metal pole that you can not walk on or use the Mach Bike on. Then you go to the far right corner and use sweet scent in the grass. You will soon find a Pikachu or Raichu.

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