Indigo is a distince blue color, and the dyes have a long history of manufacture and use. Certainly there are synthetically manufactured today as opposed to being made with Indigo tinctoria and I. suifruticosa and other legumes as they were "back in the day" when they were first being used. Links are provided to a couple of articles posted by our friends at Wikipedia, where knowledge is free.
indigo
Pigments that are made from plants and plant dyes are considered to be natural. Some examples are indigo, ultrmarine, ochres, and some reds and yellows.
there's indigo dye
Indigo is a plant that dyes fabric blue. Eliza Lucas Pinckney developed indigo as an important cash crop for South Carolina starting in 1739.
phoenecians
Shihoko Fukumoto has written: 'Shades of indigo blue' -- subject(s): Dyes and dyeing, Exhibitions, Indigo, Textile fibers 'Shihoko Fukumoto'
it was used as a dye...-------------mARzs sez..:Indigo was a highly-valued crop in British colonial Florida. One of the oldest and most-durable of dyes..
Although I'm not aware of any 'indigo' colored plants ('blue jean' or denim blue), there are some which produce naturally blue flowers: agapanthus, bachelor buttons, iris, corn flower, violets to name a few. The actual indigo plant is green, and through a process of fermentation, it produces the dark, intense indigo blue dye.
There are a large number of plant based dyes. But if you are studying the history of the American colonies, you are probably looking for Indigo.
The plant indigofera tinctorial was the source of deep blue dye before synthetic dyes were developed.
Safflower, beets, blueberries, red onion skins, brown onion skins, Indigo...
Dyes made from the shells of insects, such as cochineal, a red dye made from cockroaches