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You can evolve Riolu with the Sun Ribbon.
Some missions can give a reward. It can be a lunar ribbon.
you get it by completing the special "today's oh my gosh"
You can get the Sun Ribbon as a reward for completing a special mission in Pokemon Mystery Dungeon: Explorers of Time. The mission is called "The Mystery of the Eggs" and it involves finding Manaphy's Eggs in a dungeon. Once you complete the mission, you will receive the Sun Ribbon as a reward.
If you have Pokemon mystery dungeon explorers of sky after you complete the third special episode your rewarded a sun ribbon
you need a sun ribbon and its IQ needs to be 1 star
find it in a dungeon
To obtain a Lunar Ribbon in Pokemon Mystery Dungeon: Explorers of Time/Darkness/Sky, you must first recruit Uxie, Mesprit, and Azelf. Then, go to Spacial Rift or Temporal Tower to complete a mission given by Celebi. After completing the mission, you will receive the Lunar Ribbon as a reward.
try to go to youtub. if not go to gamefaqs.
you have to have a razor fang and a lunar ribbon because normally they evolve with the razor fang at night
you have to find a sun ribbon which is only available in explorers of time.
get a sun ribbon and train for a while