at lvl 37 it learns discharge.
Pikachu can only learn Shock Wave when you use a TM. Hope this helped! =)
It learns thunderbolt at level 26.
Pikachu learn electro ball at level 18
Pikachu learns thunderbolt at level 26.
Pikachu learns slam at level 21.
Pikachu learns Thunderbolt at level 29.Pikachu learns Thunderbolt at Level 29.
Pikachu does not learn Rock Slide from level. I think that you have to teach it Rock Slide.
As of the Pokemon Diamond and Pearl games, Pikachu learn the following moves:Egg moves - Bide, Charge, Doubleslap, Encore, Fake Out, Present, Reversal, Thunderpunch, Tickle, Volt Tackle, WishPichu moves - Charm, Sweet Kiss, Nasty PlotStart moves - Thundershock, GrowlLevel 6 - Tail WhipLevel 10 - Thunder WaveLevel 13 - Quick AttackLevel 18 - Double TeamLevel 21 - SlamLevel 26 - ThunderboltLevel 29 - FeintLevel 34 - AgilityLevel 37 - DischargeLevel 42 - Light ScreenLevel 45 - ThunderPikachu will learn: thundershock, growl, thunder wave, quick attack, swift, agility, and thunder. Any other moves Pikachu is compatible with, may be learned by certain TM and/or HM moves.
Level 36
pikachu learns thunderbolt at level 26
It should learn it around level 45 or 50 if you don't want to wait then use the TM23.
In Pokémon Mystery Dungeon: Explorers of Darkness, Pikachu learns Thunderbolt at level 26. This powerful Electric-type move is a significant upgrade from its earlier moves, offering higher damage and a chance to paralyze opponents. Players can use it strategically to enhance Pikachu’s effectiveness in battles against various foes in the game.