Ampharos learns moves from level 1 to level 68. It's best and final move to learn is Thunder.
No, it can't learn Blizzard. It can't even learn any Ice Moves at all.
Very good! It can learn really cool moves and is very loyal.
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Tackle - 1Growl - 5Thundershock - 10Thunderwave - 14Cotton spore - 19Charge - 23Discharge - 28Signal beam - 32Light screen - 37Power gem - 41Thunder - 46Note: These moves are for if you DON'T evolve Mareep into Flaaffy or Ampharos (at level 15 and 30), so please don't get annoyed if your Mareep doesn't learn all of these at these levels because you have evolved it.
Cyndiquil can learn the same moves as Quilava and Typhlosion, just at lower levels.
Lv42
Mew learns a move every 10 levels.
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Focus punch and psychic
Level 34.
Use Tms so it can learn moves at any level
Unfortunately, the only Pokemon that can learn Volt Tackle naturally is Pichu. The only physical Electric move that Ampharos gets is Thunderpunch.