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A very mild acidic cleaner

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For light rust, soak in penetrating oil (I like KROIL, but PB Blaster is good also) overnight. Rub with clean coarse cloth, such as burlap. Deeper rust may require stronger methods. Try a copper pot scrubber, such as a Chore Boy pad, toether with the oil. INSIDE the barrel, use a good bore cleaner, and a bronze bore brush.

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