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The Chinese as they invented black powder. Their first chronicled use of fire spears, or fire lances, was in 1132 at the siege of De'an.

http://en.wikipedia.org/wiki/Gunpowder

And for an idea of what a fire-spear/fire-lance is:

http://en.wikipedia.org/wiki/Fire_lance

Because of the early uses of black powder and such, we probably never will know who exactly made the first ammunition for firearms.

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13y ago

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