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The only way to get palkia's orb is when you play on Pearl and you go fight Palkia. When you capture him, go to the back of the room, and you will find an item. It holds the orb for Palkia.

Same thing for Diagla, just on Diamond and the item holds the orb for Diagla in the back.

I don't remember if the orb is the same for both, or they both have separate orbs just for them.

!! XD =D

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Q: Palikias orb on Pokemon Diamond and Pearl?
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Pokemon pearl How do you get the admin orb?

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