Aluminum is reduced.
Zinc ions are formed.
The difference between electrolytic refining and electrolytic reduction is as follows: a. In electrolytic reduction graphite electrodes are used which are of same size. in electrolytic refining the anode is made of the impure metal which is to be purified and the cathode is made from that pure metal. initially the cathode is thick and the anode is very thin. b. the electrolyte used in electrolytic refining is the metal sulphate with acid (acid id added to increase the conductivity) which is aqueous in nature. whereas in electrolytic reduction molten chloride form of the solution is used. c. The impure metal at the anode displaces the metal from the aqueous solution and the these ions go to the cathode and attach to the cathode as they are now pure. basically the impure metal at the anode directly doesn't go to the cathode, its a indirect process. as the reaction goes on, the size of the anode reduces and finally disappears and the cathode becomes thick as all the impure metal is converted into pure metal. this happens in electrolytic refining. whereas in electrolytic reduction the metal from the molten solution deposits on the cathode and chlorine gas is evolved at the anode. general differences: a. in electrolytic reduction no anode mud is formed and in electrolytic refining anode mud is formed from the impurities oh the impure metal. b. electrolytic reduction is done to extract metals of high reactivity from their ores. electrlolytic refining is done to purify (refine) metals from their impure form.
*electrolytic cells Oxidation occurs at the cathode
Cathode
Ni(s)
Ni(s)
Reduction occurs at the cathode in an electrolytic cell.
The difference between electrolytic refining and electrolytic reduction is as follows: a. In electrolytic reduction graphite electrodes are used which are of same size. in electrolytic refining the anode is made of the impure metal which is to be purified and the cathode is made from that pure metal. initially the cathode is thick and the anode is very thin. b. the electrolyte used in electrolytic refining is the metal sulphate with acid (acid id added to increase the conductivity) which is aqueous in nature. whereas in electrolytic reduction molten chloride form of the solution is used. c. The impure metal at the anode displaces the metal from the aqueous solution and the these ions go to the cathode and attach to the cathode as they are now pure. basically the impure metal at the anode directly doesn't go to the cathode, its a indirect process. as the reaction goes on, the size of the anode reduces and finally disappears and the cathode becomes thick as all the impure metal is converted into pure metal. this happens in electrolytic refining. whereas in electrolytic reduction the metal from the molten solution deposits on the cathode and chlorine gas is evolved at the anode. general differences: a. in electrolytic reduction no anode mud is formed and in electrolytic refining anode mud is formed from the impurities oh the impure metal. b. electrolytic reduction is done to extract metals of high reactivity from their ores. electrlolytic refining is done to purify (refine) metals from their impure form.
*electrolytic cells Oxidation occurs at the cathode
In an electrolytic cell
Electron flow is from anode (+) to cathode (-)
Cathode
The electrode where reduction occurs
cathode
Electrodes, the positive side is called the Cathode and the Negative side is called the Anode.The anode and cathode. The anode is positively charged and the cathode is negative.
In electrolytic decomposition, there are separate reactions at the two electrodes: At the cathode, Na+ + e- -> Na (s) and at the anode, 2 Cl- -> Cl2 + 2 e-.
Ni(s)
Ni(s)