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Both are the same. The right terminology is "Safety boots, safety shoes or safety footwear". It doesn't matter what the toe cap is made of, as long as it meets the specifications set forward by the government (in Europe EN-20345)

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Steel caps are worn on the outside of the shoe, and can be purchased separately. Steel toes are built into the shoe so that the steel isn't showing. For safety shoes both must meet or exceed standards in the U.S. under ANSI Z41.1-1967.

see link below for a few examples of toe caps.

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Q: What is the difference between a steel toe and a steel cap boots?
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