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Water is rather unique among substances. It increases its density with cooling until it reaches 4oC (Above freezing) at that time getting cooler lowers its density. As a consequence the coldest water floats on top of the above freezing point water. The ice (when it forms) is even less dense and floats at the top of the pond on the colder and warmer water. As a consequence the water that freezes is nearest the top.

Even if the water were to be cooled from the bottom, the coldest water would float to the top and when the whole pond became 0°C the ice would float to the top as it formed. In some cases where rocks are below the freezing point (exposed to the air part of the time, ice can form and stick to the rocks under water. There is one unusual case where ice crystals form as needle shaped crystals in the water below the surface. This is called frazil ice. These crystals mat together and block inlet pipes and simiar structures.

In most ponds, however, the water is losing the majority of its heat to the colder air above it, so the ice would form there. And, being less dense than water, the ice would stay on the top as does the coldest water.

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Q: Why do pond freeze from bottom to top?
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