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Why metal oxide are basic in nature?

Updated: 9/26/2023
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8y ago

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The oxide ions in a metal oxide generally react with water to form hydroxide ions which are basic in nature (OH-). Here's a complete reaction example :

The oxide ion tends to react with water to form hydroxide ions.

generically O2- + H2O --> 2OH-

As an example, CaO + H2O ---> Ca(OH)2

Some other metal oxides (like ZnO and Al2O3) are basic BUT also acidic oxides:

ZnO + H2O + 2 OH- --> Zn(OH)42- in which reaction hydroxide is needed and NOT formed! This behaviour is usually termed amphoteric.

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Heather Tremblay

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Q: Why metal oxide are basic in nature?
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A metallic oxide is basic in nature.


Is metal oxide is a base?

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metallic oxide react with water to form its hydroxides. all these metal oxide are basic in nature due to more electropositive nature of metal atom. EX. M2O + H2O --> 2MaOH The alkali metal oxides M2O (M = Li, Na, K, Rb) Na2O + H2O --> 2NaOH sodium oxide dissolve in water afford sodium hydroxide


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