The gospel of John is not part of the Synoptic Gospels.
The gospels of Matthew, Mark, and Luke are referred to as the Synoptic Gospels.
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Luke
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The book of Luke.
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John's Gospel records seven miracles, which is less than in the
synoptic Gospels.
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There is no whole or fragmentary synoptic gospel manuscript dating before 100 CE. Rather than review what does exist, another answer on this site provides an exhaustive survey of surviving synoptic manuscripts: click here.