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No.

Vanilla is too concentrated and strong for a rabbit. You shouldn't give your bunny any oils, dried spices/herbs, extracts, flavourings, seasonings, or anything like that. It isn't natural or healthy for rabbits to eat or drink them, and it could lead to a bad health reaction.

Putting vanilla in the water won't help with the urine smell, anyway. The smell comes from two things (mainly): hormones in your rabbit's body, especially if your bunny isn't spayed or neutered; and ammonia, which starts to grow once it leaves the rabbit's body.

The only thing you can do to to help with the urine smell is to keep the rabbit's litter and habitat clean. Scoop out soiled litter every day, and scrub down all surfaces as needed (depends on your rabbit's behaviour - maybe as often as once a month, but at least once a year).

If your rabbit is dehydrated, or sick, that could make the smell worse. Look for other signs of ill health, and consider bringing your bunny to the vet.

See the related questions below for more info.

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Q: Can you put vanilla in the rabbit's water to help with the urine smell?
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