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No, there is powdered milk and sugar in the mix and not as much cocoa. It would never have enough chocolate flavor.

Edited 7-02-12

Well, this is true, it wont have as much chocolate flavor but yes you can substitute it. Double or quadruple the the amount of cocoa powder for Hot Chocolate mix (taking out the marshmallows) (depending on your tastes) and use about 1/4 the sugar needed in the recipe. (I just made chocolate no bakes without milk and hot chocolate mix and they taste great!) I hope this helps, if you are trying to sub it in a dough mix be aware that since you will have to use more hot chocolate powder than you would cocoa you may want to mix the powder with whatever liquids you have to work with in the recipe first (to dissolve the powder and keep it from getting cakey and dry). If that doesn't work add a small amount of water or milk to the mix to get it to the right consistency. :) Hope this helped.

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