You would not say "the America", and you would not say "the China". When you are talking about a country (not a nation) or a continent, it will usually be without the definite article (the). Many nations, on the other hand have official names that say something about them politically, or about how their government is organized. So you could say "I am visiting China next year" or you could say " I am going to the People's Republic of China". By the way, "The Republic of China" refers to Taiwan, and not mainland China.
No, "an India" is not grammatically correct.You can use an before Indian. For example:We went antique shopping and found an Indian vase.
India
The Lodhi Dynasty ruled India before the advent of Mughals.
They migrated to India before writing the Vedas
No, I have not visited India before obtaining a visa.
Lion was the national animal of India before 1972.
Australia organised the Commonwealth Games before India did.
India
Only Pakistan was part of India before independence.
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India was rich, but the English developed India. They started the development of India, which Nehru continued.
Before 1947, India was represented by a Viceroy The last one was Lord Louis Mountbatten, who became India's Governor General after partition