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dicuss the significance of the Ksp of AgCl on the accuracy of the mohr's test

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Q: Discuss the significance of the Ksp of AgCl on the accuracy of the Mohr test?
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What is a mohr method?

Mohr method is a Precipitation titrations method which is the concentration of an unknown substance in solution is determined by adding measured amount of a standard solution such as AgNO3 that react with unknown samples to determine CL, Br in Solid and solutions samples . NaCL + AgNO3 =====> AgCL + NaNO3. Br- + Ag NO3=====> AgBr + NO3- Then the concentration of the unkown can be calculated using the stoichiometry of the recation and the number of moles of standard solution needed to reach the End point. The mohr method uses chromate CrO4 2- ion as an indicator . By Known the stoichiometry and moles consumed at end point,we can determine the mount of chloride in an unknown samples. Saeed Yousef AL-Soumali


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